Research @ UVA
12. Secondary-Sphere Effects in Molecular Electrocatalytic CO2 Reduction
11. Electrocatalytic Reduction of Oxygen by Mn(III) meso-Tetra(N-methylpyridinium-4-yl)porphyrin in Universal Buffer
10. Metal-Organic Frameworks as Porous Templates for Enhanced Cobalt Oxide Electrocatalyst Performance
9. A Look at Periodic Trends in d-Block Molecular Electrocatalysts for CO2 Reduction
Jiang, C.; Nichols, A.W.; Machan, Charles W.* Dalton Transactions 2019 DOI: 10.1039/C9DT00491B
8. Recent Advances in Spectroelectrochemistry Related to Molecular Catalytic Processes
Machan, C.W.* Current Opinion in Electrochemistry 2019 DOI: 10.10.1016/j.coelec.2019.03.010
7. Metal-Free Electrochemical Reduction of Carbon Dioxide Mediated by Cyclic(Alkyl)(Amino) Carbenes
6. Dioxygen Reduction to Hydrogen Peroxide by a Molecular Mn Complex: Mechanistic Divergence Between Homogeneous and Heterogeneous Reductants
Hooe, S.L. and Machan, C.W. Journal of the American Chemical Society 2019 DOI: 10.1021/jacs.8b13373
5. Nitric oxide activation facilitated by cooperative multimetallic electron transfer within an iron-functionalized polyoxovanadate–alkoxide cluster
4. Electrochemical Reduction of Carbon Dioxide with a Molecular Polypyridyl Nickel Complex
Lieske, L.E.; Rheingold, A.L.; Machan, C.W. Sustainable Energy & Fuels 2018 DOI: 10.1039/C8SE00027A
3. Reversible Modulation of the Redox Characteristics of Acid-Sensitive Molybdenum and Tungsten Scorpionate Complexes
2. Electrocatalytic Reduction of CO2 to Formate by an Iron Schiff Base Complex
1. Electrocatalytic Reduction of Dioxygen to Hydrogen Peroxide by a Molecular Manganese Complex with a Bipyridine-Containing Schiff Base Ligand
Hooe, S.L.; Rheingold, A.L.; Machan, C.W. J. Am. Chem. Soc. 2018, DOI: 10.1021/jacs.7b09027
Postdoctoral Research
17. Charged Macromolecular Rhenium Bipyridine Catalysts with Tunable CO2 Reduction Potentials
16. Concerted One-Electron Two-Proton Transfer Processes in Models Inspired by the Tyr-His Couple of Photosystem II
15. Bio-inspired CO2 reduction by a rhenium tricarbonyl bipyridine-based catalyst appended to amino acids and peptidic platforms: incorporating proton relays and hydrogen-bonding functional groups
14. Electrocatalytic Reduction of Carbon Dioxide with Mn(terpyridine) Carbonyl Complexes
13. Interrogating Heterobimetallic Co-Catalytic Responses for the Electrocatalytic Reduction of CO2 Using Supramolecular Assembly
12. Improving the Efficiency and Activity of Electrocatalysts for the Reduction of CO2 Through Supramolecular Assembly with Amino Acid-Modified Ligands
11. Re(I) NHC Complexes for Electrocatalytic Conversion of CO2
10. Photocatalytic Reduction of Carbon Dioxide to CO and HCO2H Using fac-Mn(CN)(bpy)(CO)3
9. Rapid synthesis of redox-active dodecaborane B12(OR)12 clusters under ambient conditions
8. Orientation of Immobilized Cyano-Substituted Bipyridine Re(I) fac-Tricarbonyl Electrocatalysts on Au Surfaces
7. Electrocatalytic Reduction of Carbon Dioxide by Mn(CN)(2,2ʹ-bipyridine(CO)3: CN Coordination Alters Mechanism
6. Reductive Disproportionation of Carbon Dioxide by an Alkyl-Functionalized Pyridine Monoimine Re(I) fac-tricarbonyl Electrocatalyst
5. A Molecular Ruthenium Electrocatalyst for the Reduction of Carbon Dioxide to CO and Formate
4. Synthesis, Spectroscopy, and Electrochemistry of (α-diimine)M(CO)3Br, M = Mn, Re, Complexes: Ligands Isoelectronic to Bipyridyl Show Differences in CO2 Reduction
3. Supramolecular Assembly Promotes the Electrocatalytic Reduction of Carbon Dioxide by Re(I) Bipyridine Catalysts at a Lower Overpotential
2. Combined Steric and Electronic Effects of Positional Substitution on Dimethyl-Bipyridine Rhenium(I) Tricarbonyl Electrocatalysts for the Reduction of CO<sub>2</sub>
1. Developing a Mechanistic Understanding of Molecular Electrocatalysts for CO2 Reduction Using Infrared Spectroelectrochemistry
Graduate Research
7. General Strategy for the Synthesis of Rigid Higher-Order Platinum(II) Complexes via the Weak-Link Approach: Tweezers, Triple-Layers and Macrocycles
6. One-Pot Synthesis of an Fe(II) Bisterpyridine Complex with Allosterically Regulated Electronic Properties
5. Crystallographic Snapshots of the Bond-Breaking Isomerization Reactions of Ni(II) Complexes with Hemilabile Ligands
4. A Coordination Chemistry Dichotomy for Icosahedral Carborane-Based Ligands
Spokoyny, A.M.; Machan, C.W.; Clingerman, D.J.; Rosen, M.S.; Wiester, M.J.; Kennedy, R.D.; Sarjeant, A.A.; Stern, C.L.; Mirkin, C.A.; Nat. Chem. 2011, 3, 590 Highlight by A. Weller, ibid.